Chiral Neutral Zirconium Amidate Complexes for the Asymmetric Hydroamination of Alkenes
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چکیده
منابع مشابه
Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism.
A new class of chiral zirconium complexes supported by chiral tridentate [O(-)NO(-)]-type of ligands derived from amino acids were synthesized and structurally characterized. They catalyzed asymmetric hydroamination/cyclization of primary aminoalkenes to give five- and six-membered N-heterocyclic amines with up to 94% ee.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2009
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.200990205